Try this http://gpass1.com/gpass/
1.Download Gpass
2.Double Click Gpass
3.Open SocksCap V2
4.Click File-settings in SocksCap V2
5.Socks server: 127.0.0.1 port: 8000 "select Attempt local then remote"
6.Click apply
7.Open paltalk from SocksCap V2

You can use other programs other than Gpass to login to paltalk with the exact same steps except you need to change the port depending on the program.
List of programs:
Gpass port= 8000
Freegate port= 8580
Ultrasurf port= 9666
GTunnel port= 8081

Download links:
Gpass= http://gpass1.com/gpass
Freegate= http://www.dit-inc.us
UltraSurf= http://www.ultrareach.com
GTunnel= http://gardennetworks.org

Enjoy